Reaxis® C214 - Dioctyltin bis-(isooctyl mercaptoacetate)
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REAXIS® C214, Dioctyl bis-(isooctyl mercaptoacetate), also known as Dioctyl tin-S,S’-bis(isooctylmercaptoacetate), is an octyl-based dialkyl organotin with added functionalities. Dioctyl bis-(isooctyl mercaptoacetate) has the characteristic reactivity of Sn (IV) organotin catalysts, with improved upfront delay and improved hydrolytic stability due to the presence of a sulfur-based ligand. Used primarily in polyurethanes, Dioctyl bis-(isooctyl mercaptoacetate) imparts more controlled reactivity versus standard metal carboxylates such as REAXIS® C218 (Dibutyltin Dilaurate), REAXIS® C216 (Dioctyltin Dilaurate), and REAXIS® C325 (Dimethyltin Dineodecanoate). Tin catalysts similar to REAXIS® C214 include REAXIS® C319 (Dibutyltin Mercaptide), REAXIS® C320 (Dioctyltin Mercaptide), REAXIS® C227 (Dibutyltin bis-(1-thioglycerol)), and its isomer, REAXIS® C416 (Dioctyltin bis-(2-Ethylhexyl Mercaptocetate)).
For more information, we invite you to read our technical bulletins on Iron Catalysts and Strategies for Improving Back-End Reactivity of Bismuth Carboxylate catalysts.
Technical Information
- Product Category Organotin
- Chemical Name Dioctyltin bis-(isooctyl mercaptoacetate)
- CAS Number 26401-97-8
Typical Specifications
Parameter | Range |
---|---|
Refractive Index (nD @20°C) | 1.485 - 1.500 |
Color (Gardner Number) | 5 Max |
Density (g/ml) | 1.045 - 1.070 |
Tin Content (%) | 14.5 - 16.0 |
International Regulatory Listings
- TSCA (US) Yes
- DSL (Canada) Yes
- AICS (Australia) Yes
- KECI (South Korea) Yes
- IECSC (China) Yes
- ENCS (Japan) Yes
- TCSI (Taiwan) Yes
- NZloC (New Zealand) Yes
- PICCS (The Philippines) Yes
- REACH (EU) No
- NDSL (Canada) No
Applications
Unlike standard organotin carboxylates, sulfur-bearing organotins are primarily used as a catalyst for polyurethanes. Catalysts like REAXIS® C214 tend to be inactive in silicone and esterification-related applications. Since the sulfur ligand acts as a blocking agent, thermal deblocking is required to initiate the back-end cure. Thus, tin catalysts such as REAXIS® C214 tend to perform best in adhesive, elastomer, and foam applications with adequate exotherms. For coatings applications, REAXIS® C214 can be used in baked cured systems in contrast to ambient cured systems. As an octyltin, REAXIS® C214 is a good replacement in some cases for butyl-based tins such as REAXIS® C319.
Reactivity
As is typical of most organotin and inorganic tin catalysts, the specific ligand contributes a major influence on overall reactivity. This is specifically highlighted in regard to sulfur-bearing ligands. In general, these sulfur ligands impart improved front-end delay and hydrolytic stability versus standard tin carboxylates. Standard ligands include thiols, mercaptides and mercaptoacetates. Reactivity, as defined by delay, thermal availability, hydrolytic stability, and final cure will depend on the specific ligand, tin content, alkyl group and, most importantly, other raw materials used in the specific polyurethane formulation. As Dioctyl bis-(isooctyl mercaptoacetate) is a mercaptoacetate-based catalyst, its delay should be more pronounced compared with mercaptans such REAXIS® C319 and REAXIS® C320. In regard to the reactivity of the various urethane reactions, catalysts such as REAXIS® C214 will selectively catalyze the isocyanate-polyol reaction, with less of an effect on the water reaction.
Package & Storage
- 485lb (220 kg) steel drums
- 44 lb (20 kg) plastic pails
REAXIS® C214 should be stored in the original packaging at moderate temperatures and kept from freezing. The container should be closed tightly after each use to maximize shelf life. Characteristic of most Sn (IV) organotins, the primary cause of instability would be hydrolysis. Although more stable compared to organotin carboxylates, long-term contact with moisture could result in hydrolysis with the formation of tin oxide insolubles leading to deactivation of REAXIS® C214.
Safety and Handling
Hazard Classification (US SDS)
Section | Hazard Class | Category | Hazard Statement |
---|---|---|---|
A.10 | acute toxicity (oral) | 4 | H302 |
A.9 | specific target organ toxicity - repeated exposure | 1 | H372 |
Hazard Pictograms (US SDS)
Transportation Information (US SDS)
DOT | IMDG | ICAO | Environment Hazard | |
---|---|---|---|---|
UN Number | not subject to transport regulations | not subject to transport regulations | not subject to transport regulations | non-environmentally hazardous acc. to the dangerous goods regulations |
UN Proper Shipping Name | None | None | None | |
Transport Class | None | None | None | |
Packing Group | None | None | None |
Primary Composition Substance(s)
- dioctyltin bis(isooctyl mercaptoacetate)
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