Overview
REAXIS® C248LC (Dibutyltin Oxide-Low Chloride) is a dialkyl organotin typically used as a catalyst in E-coat formulations and esterifications. Commonly referred to as DBTO or Dibutyloxotin, Dibutyltin Oxide is characterized by a high tin content (~ 48%), low chloride content, controlled particle size distribution and an oxide ligand, all of which impart both high reactivity and high-temperature stability. REAXIS® C248LC is supplied as a solid and can be supplied as a stable liquid with suitable diluents such as plasticizers and silanes. Related liquid-grade versions include REAXIS® C248D, which includes a plasticizer and a relatively high tin content, REAXIS® C248DP, which contains a plasticizer and lower tin content, REAXIS® C248DN, which also contains a plasticizer but has a lower overall tin volume, REAXIS® C248T, which contains a silane complex, and REAXIS® C248VM, which is another variant of our DBTO and silane compound. These liquid versions are used as catalysts for silicone condensation reactions. REAXIS® C248 is the standard solid-grade version.
Technical Information
- Product Category Organotin
- Chemical Name Dibutyltin Oxide
- CAS Number 818-08-6
Typical Specifications
| Parameter | Range |
|---|---|
| Tin Content (%) | 47.0 Min |
| Chloride (%) | 500 Max |
| Moisture (%) | 0.5 Max |
| Fe (ppm) | 10 Max |
International Regulatory Listings
- TSCA (US) Yes
- DSL (Canada) Yes
- AICS (Australia) Yes
- KECI (South Korea) Yes
- IECSC (China) Yes
- ENCS (Japan) Yes
- TCSI (Taiwan) Yes
- NZloC (New Zealand) Yes
- PICCS (The Philippines) Yes
Applications
REAXIS® C248LC is are used in electro-coat (E-coat) applications, where it is preferred due to the more controlled particle size and lower chlorides. REAXIS® C248LC is used as a homogenous catalyst for fatty acid-based saturated and unsaturated monomeric and polymeric esters. REAXIS® C248LC can be used as a transesterification catalyst and is thus used in the synthesis of alkyd resins. In its plasticizer and silane liquid forms, Dibutyltin Oxide is a good silicone condensation catalyst for adhesive, sealant, and coatings formulations, especially those formulations using silane-terminated polymers (STPs). Alternative catalysts for esterification reactions include REAXIS® C220 (Monobutyltin Tris-(Ethylhexanaote)), REAXIS® C160 (Stannous Oxalate) and REAXIS® C129 (Stannous Octoate).
Reactivity
REAXIS® C248LC has a few characteristics that make it a suitable catalyst for a wide range of high-temperature esterification reactions. These include a high active tin content, dialkyl content and the presence of an oxide ligand. These characteristics result in a tin catalyst with good compatibility in a wide range of ester formulations, high reactivity leading to lower reaction times and the synthesis of low color end products, stability at typical reaction temperatures (180-230°C), and hydrolytic stability in the presence of water generated during esterification.
Package & Storage
- 20kg (44lb) pails
REAXIS® C248LC should be stored in the original packaging at moderate temperatures. The container should be closed tightly after each use to maximize shelf life.
Safety and Handling
Hazard Classification (US SDS)
| Section | Hazard Class | Category | Hazard Statement |
|---|---|---|---|
| A.10 | acute toxicity (oral) | 3 | H301 |
| A.2 | skin corrosion/irritation | 2 | H315 |
| A.3 | serious eye damage/eye irritation | 1 | H318 |
| A.4S | skin sensitization | 1 | H317 |
| A.5 | germ cell mutagenicity | 2 | H341 |
| A.7 | reproductive toxicity | 1B | H360FD |
| A.8 | specific target organ toxicity - single exposure | 1 | H370 |
| A.9 | specific target organ toxicity - repeated exposure | 1 | H372 |
Hazard Pictograms (US SDS)
Transportation Information (US SDS)
| DOT | IMDG | ICAO | Environment Hazard | |
|---|---|---|---|---|
| UN Number | UN 3146 | UN 3146 | UN 3146 | hazardous to the aquatic environment |
| UN Proper Shipping Name | Organotin compound, solid, n.o.s | ORGANOTIN COMPOUND, SOLID, N.O.S | Organotin compound, solid, n.o.s | |
| Transport Class | 6.1 | 6.1 | 6.1 | |
| Packing Group | lll | lll | lll | |
Primary Composition Substance(s)
- Dibutyltin oxide
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This information is provided to the best of our knowledge but without obligation. Reaxis is not liable for any incorrect or missing information. This data sheet becomes invalid upon publication of a new version. Please contact us for the latest version.
