Reaxis® C2013 - Dioctyltin Diacetyl Acetonate
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REAXIS® C2013 (Dioctyl Tin bis-(Acetylacetonate)) is an octyl-based organotin with a ketonate functionality. REAXIS® C2013 is a highly reactive neat liquid butyl tin catalyst given its high tin content (23%) and related small ligand. REAXIS® C2013 is part of the tin (IV) family of organotins. Due to its ketonate-based ligand, REAXIS® C226 has a reduced hydrolytic stability compared to carboxylate functionalized organotins such as REAXIS® C218 (Dibutyl Tin Dilaurate). REAXIS® C2013 is an octyltin and tends to be slower in reactivity when compared to its butyl analogue, REAXIS® C226 (Dibutyltin Bis-Acetylacetonate). Products with similar reactivity include REAXIS® C417V (Dioctyltin Oxide + Silane Complex), REAXIS® C417VM (Dioctyl tin Oxide + VTMO) and REAXIS® C417 (Dioctyl tin Oxide + TPOS). REAXIS® C2013 is on limited international regulatory lists for commercial use. REAXIS® C2013 has only a limited Low Volume Exemption TSCA status and is not listed on Canada’s DSL or NDSL. REAXIS® C2013 is only sold for commercial use in the EU.
Technical Information
- Product Category Organotin
- Chemical Name Dioctyltin Diacetyl Acetonate
- CAS Number 54068-28-9
Typical Specifications
| Parameter | Range |
|---|---|
| Density (g/ml) | 1.0 - 1.2 |
| Tin Content (%) | 20.0 - 22.0 |
| Color (Gardner Number) | 5 Max |
International Regulatory Listings
- REACH (EU) Yes
- TSCA (US) No
- DSL (Canada) No
- NDSL (Canada) No
- AICS (Australia) No
- KECI (South Korea) No
- IECSC (China) No
- ENCS (Japan) No
- TCSI (Taiwan) Yes
- NZloC (New Zealand) Yes
- PICCS (The Philippines) No
Applications
REAXIS® C2013 and its alternatives can be used as a homogeneous catalyst in a wide spectrum of silicone applications including adhesives, sealants, and coatings. Silicone-based applications include: acetoxy-, ethoxy- and oxime-based Room Temperature Vulcanizing (RTV) adhesives and sealants, polyethylene crosslinked silanes (PEX), and select silane-modified polymers (SMPs). REAXIS® C2013 is the primary catalyst used with MS Polymer® based formulations.
Reactivity
Given its high tin content, liquid form, small ligand, and good compatibility with a wide range of raw materials, REAXIS® C2013 tends to be a highly reactive catalyst across a broad range of silicone formulations. In regard to silicone reactions, REAXIS® C2013, like all tin-based catalysts, will catalyze the silanol/silane condensation reaction, thus acting as both a polymerization and crosslinking catalyst. REAXIS® C2013 is less hydrolytically stable toward condensation-generated moisture compared to carboxylate organotins. Reactivity-wise, REAXIS® C417VM and REAXIS® C417V would be an ideal choice in similar specialty chemical applications.
Package & Storage
- 440 lb (200 kg) steel drum
- 2400lb (1089 kg) IBC
REAXIS® C2013 should be stored in the original packaging. The container should be closed tightly after each use to maximize shelf life. Characteristic of most Sn (IV) organotins, the primary cause of instability would be hydrolysis. Hydrolysis results in the formation of tin oxide insolubles leading to deactivation of REAXIS® C2013.
Safety and Handling
Disclaimer
Hazard Classification (US SDS)
| Section | Hazard Class | Category | Hazard Statement |
|---|---|---|---|
| A.3 | skin sensitization | 1 | H317 |
| A.8 | specific target organ toxicity - single exposure | 2 | H371 |
| B.6 | flammable liquid | 4 | H227 |
Hazard Pictograms (US SDS)
Transportation Information (US SDS)
| DOT | IMDG | ICAO | Environment Hazard | |
|---|---|---|---|---|
| UN Number | not subject to transport regulations | not subject to transport regulations | not subject to transport regulations | non-environmentally hazardous acc. to the dangerous goods regulations |
| UN Proper Shipping Name | not relevant | not relevant | not relevant | |
| Transport Class | none | none | none | |
| Packing Group | not assigned | not assigned | not assigned | |
Primary Composition Substance(s)
- Tin, dioctylbis(2,4-pentanedionato-κO2,κO4)-
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This information is provided to the best of our knowledge but without obligation. Reaxis is not liable for any incorrect or missing information. This data sheet becomes invalid upon publication of a new version. Please contact us for the latest version.
