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Catalysts for Esterification Reactions

Navigating through numerous alcohol and carboxylic acid choices for esterification reactions can be overwhelming. Once you’ve chosen your starting materials, the last thing you need is to worry about finding the right metal-based catalyst. Our product portfolio of specialty metal-based catalysts covers a wide spectrum of alternative inorganic tin to organometallic products. Whether you’re facing a new challenge in ester synthesis or are a newcomer to the field, our expert technical team is also here to steer you in the right direction.

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Product List

Title Chemical Name Key Attribute 1 Key Attribute 2
Reaxis C129 Stannous Octoate Inorganic Tin(II) High Reactivity
Reaxis C154 Stannous Chloride, Dihydrate Inorganic Tin(II) High metal content
Reaxis C160 Stannous Oxalate Inorganic Tin(II) High metal content
Reaxis C162 Stannous Chloride, Anhydrous Inorganic Tin(II) High metal content
Reaxis C188 Stannous Oxide Inorganic Tin(II) High metal content
Reaxis C218 Dibutyltin Dilaurate High Reactivity Low viscosity
Reaxis C220 Monobutyltin Tris-(2-ethylhexanoate) Monoalkyl Tin Low viscosity
Reaxis C233 Dibutyltin Diacetate High metal content High Reactivity
Reaxis C248 Dibutyltin Oxide High metal content Solid
Reaxis C248LC Dibutyltin Oxide High metal content Solid
Reaxis C333W50 Water Soluble Tin Complex No Key Attribute No Key Attribute

The Role of Esterification in Industrial Manufacturing

Esterification is a pivotal process in industrial manufacturing, contributing to the production of a plethora of specialty chemical applications in the production of bulk and commodity chemicals. This chemical reaction combines an acid and an alcohol to form an ester, a component critical in various industrial applications from pharmaceuticals to adhesives and coatings[1].

The importance of esterification stems from the versatility of esters themselves. Depending on the specific acid and alcohol used, esters can have wide-ranging physical and chemical properties, making them adaptable to many different specialty chemical applications, including coatings, adhesives and sealants, composites, elastomers, personal care and lubricants.  They are utilized in adhesives and coatings due to their bonding capabilities and resistance properties, and in plastics for their flexibility and durability.[2] The uses of esters in industrial manufacturing are endless, and Reaxis is here to provide the optimum catalysts for esterification production with regard to your specific needs.

In addition to their versatility, the esterification process is commonly used due to its relative simplicity and cost-effectiveness. Under the right conditions, acids and alcohols readily react to form esters, making it an accessible reaction for many industrial processes. The ability to create complex molecules through a straightforward process underscores the esterification reaction’s importance in the chemical industry and manufacturing.[3]

Inorganic Tin and Organotin Compounds: Essential Catalysts for Esterification Reactions

Tin catalysts are commonly used in the synthesis of a wide range of mono- and polyesters and alkyds. In regard to polyesters, tin catalysts are used primarily in the production of saturated polyesters used in various coatings applications. Saturated Polyester polyols are one of the key raw materials used in producing polyurethanes.  Tin catalysts are also used in the synthesis of unsaturated polyesters,  such as those used in the production of various plastic composites. Inorganic tin and organotin catalysts such as REAXIS® C125 (Stannous Neodecanoate) REAXIS® C129 (Stannous Octoate) Stannous Chloride (both in dihydrate as REAXIS® C154 and anhydrous as REAXIS® C162), REAXIS® C160, (Stannous Oxalate) REAXIS® C188 (Stannous Oxide) REAXIS® C216  (Dioctyltin Dilaurate) REAXIS® C218  (Dibutyltin Dilaurate) REAXIS® C220 (Monobutyltin Tris-(2-Ethylhexanoate)) REAXIS® C233 (Dibutlytin Diacetate) and REAXIS® C248 (Dibutyltin Oxide) are commonly employed.

Reaxis: Supplying Key Esterification Catalysts for Industrial Manufacturing

At Reaxis, we understand the critical role esterification plays in industrial manufacturing, and we are committed to supplying high-quality, performance-enhancing inorganic tin and organotin catalysts for these processes. The aforementioned catalysts for esterification reactions are integral to our offering, each possessing unique properties that contribute to the overall efficiency and quality of industrial manufacturers’ end products. By leveraging our extensive knowledge of these catalysts and the esterification process, along with a long history of commercial production experience, we support our customers in delivering innovative and reliable chemical solutions. Find your ideal esterification catalyst amongst our list of products above, and if you’re not sure which one would suit your needs, please contact us.

References

  1. Manufacturing Chemist, “Revolutionizing industrial applications of ester hydrogenation,” https://www.manufacturingchemist.com/news/article_page/Revolutionising_industrial_applications_of_ester_hydrogenation/139571
  2. Science Direct, “A review on enzymatic synthesis of aromatic esters used as flavor ingredients for food, cosmetics and pharmaceuticals industries”
    https://www.sciencedirect.com/science/article/abs/pii/S0924224417304570
  3. American Chemical Society, “Hydrogenation of Carboxylic Acids, Esters, and Related Compounds over Heterogeneous Catalysts: A Step toward Sustainable and Carbon-Neutral Processes,” https://pubs.acs.org/doi/10.1021/acs.chemrev.2c00550